5×5棒束通道内流动转捩特性研究

棒束通道的特殊结构导致其内部流动转捩情况较为复杂，探究其内部流动转捩规律具有重要意义。本文针对棒束通道内的流动转捩特性开展实验与CFD模拟研究，通过实验获得了棒束通道内沿程阻力系数的变化规律；采用不同湍流模型进行了数值模拟。结果表明，SST k-ω模型能较好地反映实验结果。进一步对比了不同雷诺数工况下通道内不同位置的沿程阻力系数与湍流强度，发现对于不同子通道，中心子通道湍流强度与沿程阻力系数高于边角子通道；对于同一子通道，子通道中心处湍流强度与壁面切应力高于子通道边缘处。这一结果说明，受壁面影响，棒束内湍流强度、壁面切应力、阻力特性具有不均匀性，这些空间上的不均匀性相互作用会引起总体上棒束转捩点不明显。     

Design standardization of unit operations for reducing the capital intensity and cost of small-scale chemical processes

A methodology is proposed to reduce the cost and capital intensity of small-scale chemical processes by creating new opportunities for economies of numbers through standardizing the equipment designs across multiple processes. We depart from asynchronous design of single-processes and adopt a common-functionality based simultaneous design of multiple processes that use similar unit operations. A generalized cost function is used to appropriately balance the trade-offs between economies of scale and economies of numbers. An optimization-based framework for design standardization is developed and illustrated using two case studies. The first involves the simultaneous synthesis of methanol and ammonia processes, and the second addresses the optimal synthesis of multi-column natural gas liquid (NGL) fractionation processes for different natural gas sources. We observe that considerable reduction in capital intensity of small-scale processes is possible through equipment standardization.     

金属有机框架化合物在荧光识别方面的研究进展

通过荧光识别化合物是一种简单可靠、方便快捷的一种分析手段。金属有机框架(metalorganic frameworks, MOFs)通过框架和客体分子之间的相互作用,在荧光识别和传感等领域有着广阔的应用前景而成为一个热点研究领域。主要综述了金属有机框架在荧光识别溶剂小分子、离子、芳香有机分子以及气体分子等领域的研究工作。     

基于聚集诱导发光效应的高固低黏丙烯酸荧光树脂的制备及其性能研究

为了研制一种具有荧光功能特性的高固低黏羟基丙烯酸树脂。从聚集诱导发光效应（AIE）出发，将具有 AIE性质的二对丙烯酸四苯乙烯酯荧光分子通过自由基共聚连接于聚合物链段。由于聚合物链段对荧光分子化学键固定以及聚合物链的包裹束缚作用，导致荧光分子运动受限，从而实现涂层在紫外灯下荧光发光。通过荧光光谱的实时跟踪，探索高固低黏羟基丙烯酸树脂的合成以及固化规律。此外，由于聚合物链段对外界刺激具有实时响应性，从而间接影响了所连接的荧光分子的荧光发光行为。因此，文中也探索了涂层在外界温度与化学气体的影响下所发生的荧光变化的规律，以探索其在功能涂层中应用的可行性。     

用于阀芯类零件去毛刺的磁极板优化设计与实验研究

目的 为解决阀芯类零件节流边毛刺去除不均匀和效率低下的问题，对磁极板尺寸和曲率进行规律性研究和实验验证。方法 首先，用Maxwell仿真软件对磁极板的各个参数进行规律性仿真，得出合适的磁极板尺寸;其次，为提高加工区域的磁感应强度值，设计了曲面磁极板，并对其相关参数进行仿真;最后对优化后的装置进行磁感应强度测试，并使用液体磁性磨具对45钢和阀芯棱边毛刺进行去除实验。结果 根据仿真结果发现，磁极板长度比工件大20 mm时，工件轴向磁场分布最均匀，磁极板厚度对磁场影响较小，磁极板宽度应根据加工间隙进行选择。曲面磁极板可以加强加工区域的磁感应强度值，曲率半径越小，加工区域获得的磁感应强度值越大，其中半圆形磁极板效果最佳。对装置的磁感应强度测试也表明，将工件置于磁场中后，其表面磁感应强度值最高达600 mT左右，满足加工需求。最后通过加工实验发现，在转速为500 r/min的条件下，阀芯节流边的毛刺去除效果理想，且轴向加工均匀。结论 该装置可以对阀芯这类导磁性回转类零件产生良好的加工效果。     

基于近场动力学方法的含缺陷板Ⅰ型应力强度因子计算

针对含多缺陷板脆性断裂问题,引入非局部近场动力学理论,结合J积分计算含缺陷板Ⅰ型应力强度因子。通过含Ⅰ型单裂纹脆性板以及系列含等长双裂纹板的应力强度因子计算,验证该方法的可行性和计算精度。进一步应用于含不等长双裂纹、含孔及孔边裂纹脆性板的应力强度因子计算,验证了该方法对于计算含复杂缺陷板Ⅰ型应力强度因子的适用性,并分析了裂纹位置和长度及孔径等多缺陷板裂尖应力强度因子的影响。     

陈四楼煤矿岩巷综合机械化掘进探索

为提高岩巷单进水平，减轻职工劳动强度，在“多上设备少上人”的理念指导下，陈四楼煤矿一直在探索着岩巷快速掘进技术，先后在不同地点、不同条件下实践了6条不同设备配套形式的岩巷作业线，通过对不同岩巷作业线优缺点的对比，在探索中不断改进，使得在不同条件下的岩巷作业线形式逐渐清晰、成熟，最终总结出了适合陈四楼煤矿较为成熟的岩巷作业线，车场、联络巷等较短或拐弯较多的巷道采用耙装机+胶带输送机+采区矸石仓岩巷作业线形式，主要大巷采用液压钻车+挖掘装载机+胶带输送机+采区矸石仓岩巷作业线，与传统的人工打眼、耙矸机+矿车出矸系统比较，采用岩巷作业线平均单进水平由传统工艺的60 m/月提高到90 m/月，施工人员由12人减少到8人，极大地提升了岩巷单进水平、提高工效，降低工人劳动强度。     

Experimental studies on characteristics of fire whirl in a vertical shaft

An internal fire whirl can be generated readily in a tall shaft model with appropriate gap width at one corner. Experimental study was carried out to investigate the relationship between the characteristics of an IFW and the corner gap width in a 9‐m‐tall vertical shaft model. The vertical shaft had a 2.1 m by 2.1 m square section with gasoline pool fire of different diameters burning inside. The gap width was varied to investigate its impact on fire whirl characteristics, such as flame development, swirling intensity, flame height, flame temperature, and heat release rate of the gasoline pool fire. Vigorous flame swirling motions were generated when the ratio of the gap width to the shaft section perimeter was within the range 0.16 to 0.21. From the flame streamline angle, it was observed that the swirling component was much stronger than buoyancy component near the bottom of burning region. The swirling component decreased and became roughly the same as buoyancy near the middle. Finally, it diminished to being much weaker than buoyancy near the top of the fire. These observations suggest that the Froude number Fr decreased from a large number to 1, and then continued to decrease to 0.     

Rotatable Aggregation‐Induced‐Emission/Aggregation‐Caused‐Quenching Ratio Strategy for Real‐Time Tracking Nanoparticle Dynamics

Real‐time tracking of the dynamics change of self‐assembled nanostructures in physiological environments is crucial to improving their delivery efficiency and therapeutic effects. However, such tracking is impeded by the complex biological microenvironment leading to inhomogeneous distribution. A rotatable fluorescent ratio strategy is introduced that integrates aggregation‐induced emission (AIE) and aggregation‐caused quenching (ACQ) into one nanostructured system, termed AIE and ACQ fluorescence ratio (AAR). Following this strategy, an advanced probe, PEG^5k‐TPE₄‐ICGD₄ (PTI), is developed to track the dynamics change. The extremely sharp fluorescent changes (up to 4008‐fold) in AAR allowed for the clear distinguishing and localization of the intact state and diverse dissociated states. The spatiotemporal distribution and structural dynamics of the PTI micelles can be tracked, quantitatively analyzed in living cells and animal tissue by the real‐time ratio map, and be used to monitor other responsive nanoplatforms. With this method, the dynamics of nanoparticle in different organelles are able to be investigated and validated by transmission electron microscopy. This novel strategy is generally applicable to many self‐assembled nanostructures for understanding delivery mechanism in living systems, ultimately to enhance their performance in biomedical applications.